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There are actually a couple of different ways to log into Picasa Web Albums.
One is from Picasa – you should see a link to 'Sign in to Web Albums' in the upper right corner of Picasa's screen. Click that, fill out your username and password – then I check the box that says, “Remember me on this Computer” and click 'Sign In'. Now – in that same upper right hand corner, you should see your username and a link that says, “Web Albums” If you click on Web Albums – it will take you to the web.
Another way is on the Web. Your web albums account *is* your google account. So, if you log in to your Google Mail (gmail.com) then, you are logged in to your Google account. At the top left of the gmail screen you will see all the other Google sites available to your account: Calendar, Documents, Reader, Web, and More … If you click on More … the first item is Photos. Google Photos and Picasa Web Albums are one and the same.
Hope that helps, let us know.