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There are two ways to get your edited pictures from Picasa to Facebook:
- Install the Picasa Uploader from Facebook. This puts a Facebook button at the bottom of your Picasa window and it will upload your edited photos directly to Facebook. See specific directions in this article: Picasa to Facebook and/or watch this video Uploading to Facebook From Picasa
- Save your edits using Picasa: After editing any picture, use the File menu – Save command. Now the picture on disk is the same as the one you see in Picasa. When you upload from Facebook, you'll see the edited version.